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Clean Hydrogen Partnership

Fire in a hydro-cracking unit due to the failure of a hose

Event

Event ID
1180
Quality
Description
The incident occurred during maintenance works at a hydro-cracking unit of a refinery (the report does not explicitly mention the unit, but it is plausible to assume that it was a hydro-cracking and/or desulphurisation unit). A flexible hose ruptured releasing a flammable mixture containing hydrogen and hydrocarbons. The mixture ignited, resulting in a large fire at the refinery.

On the day of the incident, two company’s employees and one contractor’s employee were removing temporary equipment installed for the change of the reactor’s catalyst. The hose which failed was part of this equipment, connected to a flare system. The hose had a maximum pressure rating of 20 bar (300 psi). The workers, preparing to remove the temporary equipment, opened a valve that exposed the hose to a pressure above 120 bar (1,800 psi). The over-pressure broke the hose and approximately 2.9 metric tons (6,400 pounds) of flammable material.

According to the investigation performed by the company, its management of the change process for the temporary equipment was missing information.
The piping and instrumentation diagram did not identify hoses, and the review team assumed that piping with an appropriate pressure rating was used. However, the team responsible for the pre-startup safety review incorrectly concluded that the hose’s pressure rating was sufficient.
Another finding was that the company did not apply other management systems, including a job safety analysis, and did not develop a procedure detailing the correct order to open the valves, as they were not identified as necessary for temporary equipment.
Event Initiating system
Classification of the physical effects
Hydrogen Release and Ignition
Nature of the consequences
Fire (No additional details provided)
Macro-region
North America
Country
United States
Date
Main component involved?
Hose (Generic)
How was it involved?
Rupture & Formation Of A Flammable H2-Hc-Air Mixture
Initiating cause
Over-Pressurisation
Root causes
Root CAUSE analysis
The INITIATING CAUSE was the over-pressurisation and failure of a flexible hose used a temporary set-up during maintenance.
The ROOT CAUSE was lack of a proper management if change and the failing to execute a correct risk assessment of the maintenance and start-up operations.

Facility

Application
Petrochemical Industry
Sub-application
hydro-treatment
Hydrogen supply chain stage
All components affected
hose
Location type
Open
Location description
Industrial Area
Operational condition
Pre-event occurrences
The plant was being restarted.

Emergency & Consequences

Number of injured persons
0
Number of fatalities
0
Environmental damage
0
Currency
US$
Property loss (onsite)
2300000

Lesson Learnt

Lesson Learnt

According to the CSB report, “the probable cause of the incident was the overpressure of a temporary hose. Contributing to the incident was not recognizing the potential to overpressure the hose, resulting from misunderstandings during the management of change process and an ineffective pre-startup safety review.”
The incident could have been avoided, if the company would have performed an effective hazard analysis and risk assessment of all operations occurring after the maintenance and during the pre-startup phase. This assessment would have identified the mismatch between the equipment used and the pressure present in the unit.

Corrective Measures

After the incident, among other actions, the company approved a project to install permanent piping to prevent the need for hoses during similar catalyst replacement work in the future.

Event Nature

Release type
gas-liquid mixture
Involved substances (% vol)
H2,
hydrocarbons
Released amount
2.9 t (total)
Actual pressure (MPa)
12.4
Design pressure (MPa)
2.1
Presumed ignition source
Not reported

References

Reference & weblink

CBS incident reports volume 3, <br />
https://www.csb.gov/us-chemical-safety-board-releases-volume-3-of-chemi… />
accessed April 2025

JRC assessment