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Clean Hydrogen Partnership

Fire in a fired heater of an ethylene plant

Event

Event ID
1168
Quality
Description
An explosion of a mixture of hydrogen and hydrocarbons occurred at a fired heater of an ethylene unit of a chemical plant. The bad weather caused the shut down of the boiler units. This shutdown decreased the supply of steam and water to an ethylene unit at the facility. As designed, a safety system automatically shut the fired heater down due to insufficient steam and water flow. However, the fuel isolation valve failed to close. Without any flow through the tubes to remove heat from their walls, the tubes in the fired heater reached excessively high temperatures and some of them ruptured, likely due to short-term overheating. Hydrocarbons downstream from the fired heater were released through the broken tubes and ignited by the burner flames inside the firebox, causing a fire.
The post incident investigation determined that the fuel isolation valve could close as designed. The conclusion was that valve did not close due to frozen water from the air supply had frozen or ice formation on the external actuator components.

Source: CBS
[Note of the HIAD validator: for events triggered by the same storm, see previous #1167, occurred at a different plant, and #1056, which affected a pipeline providing hydrogen to the plants.]
Event Initiating system
Classification of the physical effects
Hydrogen Release and Ignition
Nature of the consequences
Macro-region
North America
Country
United States
Date
Main component involved?
Heat Exchanger (Pipe)
How was it involved?
Rupture
Initiating cause
Over-Heating
Root causes
Root CAUSE analysis
The INITIATING CAUSE was due to failure to close the valve providing fuel to the heaters, which then over-heated the tubes causing the release and ignition of the flammable mixture contained in them.
The IGNITION was provide by the heater flames
CONTRIBUTION and ROOT CAUSES were inadequate winterization of multiple valves, instruments, and control systems.

Facility

Application
Chemical Industry
Sub-application
ethylene production plant
Hydrogen supply chain stage
All components affected
process valve, heater tube
Location type
Confined
Location description
Industrial Area
Operational condition
Pre-event occurrences
Extreme cold weather from a winter storm caused several freeze-related operational issues.

Emergency & Consequences

Number of injured persons
0
Number of fatalities
0
Currency
US$
Property loss (onsite)
5800000

Lesson Learnt

Lesson Learnt

This event is very similar to the previous one #1167, which happened at another plan of the same company. The both occurred at the same time as the event #1056, affecting a pipeline. They all were triggered by the same extreme environmental conditions caused by a winter storm and by the measures adopted by the plans operators to face lack of feedstock supply. They happened at approximately 100 miles distance from each others.
According to CBS, to the material or component failures characterising these incidents contributed an inadequate preparation of multiple valves, instruments, and control systems to extreme weather conditions.

Event Nature

Release type
gas mixture
Involved substances (% vol)
H2, hydrocarbon
Presumed ignition source
Open flame

References

Reference & weblink

CBS incident reports volume 2<br />
https://www.csb.gov/us-chemical-safety-board-releases-volume-2-of-chemi… />
accessed April 2025

JRC assessment