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Clean Hydrogen Partnership

Release of hydrogen from LH2 storage tank

Event

Event ID
1091
Quality
Description
A leak occurred at a of a liquid withdrawal valve of a liquid hydrogen storage tank. The hydrogen escaped at the flange between the valve body and the upper part of the valve (flange with tongue and groove). 40 kg of hydrogen were lost.
The accidental release was due to the use of bolts different from those prescribed. By using the wrong ones (old bolts), the bolt material was able to flow at the specified tightening torque. This meant that there was insufficient tightening torque, which led to a leak.
Event Initiating system
Classification of the physical effects
Unignited Hydrogen Release
Nature of the consequences
Leak No Ignition (No additional details provided)
Macro-region
Europe
Country
Germany
Date
Main component involved?
Flange (Bolts)
How was it involved?
Leak & Formation Of A Flammable H2-Air Mixture
Initiating cause
Wrong Component
Root causes
Root CAUSE analysis
The INITIATING CAUSE was the lack of tightness of a flange, due to the erroneous use of bolts on a flange.

The ROOT CAUSE is related to a human error, to lack of knowledge and to the absence of clear procedures.

Facility

Application
Chemical Industry
Sub-application
Silicium single crystal manufaturing for electronics industry
Hydrogen supply chain stage
Hydrogen Storage (No additional details provided)
All components affected
flange, bolts
Location type
Unknown
Operational condition
Pre-event occurrences
The source does not mention when the wrong installation of the old bolts occurred and how much time passed between that moment and the start of the release.

Emergency & Consequences

Number of injured persons
0
Number of fatalities
0
Environmental damage
0
Property loss (onsite)
0
Property loss (offsite)
0
Post-event summary
40 kg of hydrogen were released.

Lesson Learnt

Lesson Learnt

Although the source does not provide details regarding the moment when the wrong bolts were installed, it is plausible to conclude from the available evidence that this happed during a repair or replacement phase. If correct, the event is a typical example of "things gone wrong during maintenance". The human error is only a component of the root cause, the other being a shortcoming of measures able to prevent the human error.

Corrective Measures

1. Replace bolts, nuts and spring washers according to manufacturer's instructions.
2. Check the bolts after 12 hours and re-tighten if necessary.
3. Weekly check of the tightening torques for 4 weeks, then every six months.
4. If bolts need to be tightened during the above checks, replacement of the seal should be planned.
5. Plant-specific training for staff. The number must be determined so that trained people are continuously available.
6. Setting up a camera system that provides insight into the areas of the valves and the filter skid.
7. Renewed “awareness” training for the local fire department.
8. Minimizing the time by which a competent person from a specialist company is on site.
9. Creation of work instructions for the fitters, which stipulate that when using refurbishment kits, the kit is checked and only the new components are used.

Event Nature

Release type
gas
Involved substances (% vol)
H2 100%
Released amount
40 kg
Presumed ignition source
No ignition

References

Reference & weblink

Event from German database ZEMA<br />
https://www.infosis.uba.de/index.php/en/binaries/asset/zema_ereignis/33… />
(accessed December 2023)

JRC assessment