Skip to main content
Clean Hydrogen Partnership

Fire on the hydrodesulphurisation unit of a refinery

Event

Event ID
1066
Quality
Description
A major leak occurred at the outlet of the diesel hydrodesulphurisation furnace in a refinery. The furnace was just restarting. The released gaseous product ignited, and the alarms of the temperature sensors at the oven outlet were triggered.
8 minutes later the operator shut down the hydrogen compressors and the diesel charging pumps, closed the supply valves and called the emergency status.
The internal emergency services were able to bring the situation under control, by depressurising the unit and letting the fire terminate due to lack of fuel.
The emergency plan was terminated 5 hours later and the fire gradually extinguished one hour later.

The leak occurred at the joint of a flange of the piping at the furnace outlet. This connection was not provided by evidence of controlled tightening or formal verification. Moreover, many successive shutdowns had already occurred, the last 4 the day before the event. The day before at a small leak had already been observed, but no LEL measurement had been taken, and it was decided to continue the start-up procedure.
Event Initiating system
Classification of the physical effects
Hydrogen Release and Ignition
Nature of the consequences
Fire (No additional details provided)
Macro-region
Europe
Country
France
Date
Main component involved?
Flange (Bolts)
How was it involved?
Leak & Formation Of A Flammable H2-Hc-Air Mixture
Initiating cause
Loss Of Tightness (Thermal Stress/Cycling)
Root causes
Root CAUSE analysis
Poor inspection processes and wrong assumption of the severity of the initial leak are CONTRIBUTING orROOT CAUSES. The failure to act on clear signal of malfuntioning provided by the previous mear misses (multiple shutdown, small leak detection) suggests a lack of proper risk assessment and mistaken management decisions.

Facility

Application
Petrochemical Industry
Sub-application
Hydrodesulphurisation process
Hydrogen supply chain stage
All components affected
furnace, outlet flange
Location type
Open
Location description
Industrial Area
Operational condition
Pre-event occurrences
Several successive shutdowns had already occurred, the last 4 the day before the event. The day before at a small leak had already been observed, but no LEL measurement had been taken, and it was decided to continue the start-up procedure.

Emergency & Consequences

Number of injured persons
0
Number of fatalities
0
Post-event summary
The unit was shut down for more than 35 days to allow for repair work. The material damage on the site was located within a radius of ten meters around the leak point.
The quantity of ignited product was 18 t, with an emission of 173 kg of SO2.

Event Nature

Release type
gas mixture
Involved substances (% vol)
H2,
other process gases
Released amount
18 t
Presumed ignition source
Not reported

References

Reference & weblink

JRC assessment