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Clean Hydrogen Partnership

Fire on an alkaline electrolyser

Event

Event ID
1065
Quality
Description
A fire broke out on the insulating plastic elements of an alkaline electrolyser in a unit of a chemical plant. The shift saw the smoke from the control room.
The first action was to drain the potash into a tank provided for this purpose and to shut down the electrolyser. The on-call electrician interrupted the electricity.
The safety technician brought the fire under control in less than 10 minutes using CO2 extinguishers. After approximately six hours, the unit was restarted.
Event Initiating system
Classification of the physical effects
Hydrogen Release and Ignition
Nature of the consequences
Fire (No additional details provided)
Macro-region
Europe
Country
France
Date
Main component involved?
Electrolytic Cell
How was it involved?
Fire
Initiating cause
Malfunctioning (Electrolyser, Cross-Over)
Root causes
Unknown (No additional details provided)
Root CAUSE analysis
The INITIATING CAUSE of the event was potash leak on the electrolyser block that induced an electric arc between the electric block and the bus bar. This ignition caused a rise in temperature followed by the outbreak of fire.
ROOT CAUSE unknown.

Facility

Application
Hydrogen Production
Sub-application
water electrolysis
Hydrogen supply chain stage
All components affected
Alkaline electrolyser
Location type
Unknown
Operational condition

Emergency & Consequences

Number of injured persons
0
Number of fatalities
0
Environmental damage
0
Property loss (onsite)
0
Property loss (offsite)
0

Lesson Learnt

Corrective Measures

Following the event, the operator implemented the following actions:
• Increase the frequency of predictive and preventive maintenance: preventive visit to each electrolyser with cleaning or repair if necessary;
• Add to the return of experience the occurrence of this event;
• Increase operator awareness.

Event Nature

Release type
liquid
Involved substances (% vol)
KOH (solution)
Presumed ignition source
Not reported

References

Reference & weblink

JRC assessment