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Clean Hydrogen Partnership

hydrogen and hydrocarbon release in a refinery

Event

Event ID
999
Quality
Description
The incident occurred at a reactor vessel of a naphtha hydrotreater unit. The vessel operated at around 25 bar and 140 C. A 1.5-meter crack opened up in the reactor vessel close to welded vessel support, causing the release of hot naphtha and hydrogen, which created a vapour cloud and ignited, leading to an explosion and fire. The explosion caused releases from other parts of the plant, including a nearby diesel hydrotreater, which contributed to the fire.
Eight on-site employees were injured, but there were no fatalities.
Residents of a nearby town were evacuated as a precaution.
Event Initiating system
Classification of the physical effects
Hydrogen Release and Ignition
Nature of the consequences
Macro-region
Europe
Country
Germany
Date
Main component involved?
Reactor / Oven / Furnace / Test Chamber
How was it involved?
Rupture & Formation Of A Flammable H2-Hc-Air Mixture
Initiating cause
Unknown
Root causes
Unknown (No additional details provided)
Root CAUSE analysis
The INITIATING/direct cause was the opening of crack. Details are missing for an accurate conclusion on the cause.

Facility

Application
Petrochemical Industry
Sub-application
Hydrotreater
Hydrogen supply chain stage
All components affected
reactor vessel
Location type
Open
Location description
Industrial Area
Operational condition
Description of the facility/unit/process/substances
DESCRIPTION OF THE PROCESS
The refinery started operation in 1967. The plant is located near the river Donau. It receives crude oil from a pipeline and processes it into gasoline, diesel fuel, heating oil, kerosene, bitumen and sulphur.

Emergency & Consequences

Number of injured persons
12
Number of fatalities
0
Currency
US$
Property loss (onsite)
824000000
Property loss (offsite)
4900000
Post-event summary
Some refinery process units were extensively damaged as a result of the explosion and fire, as well as multiple office and maintenance buildings within the refinery site. Windows in a village at least 3km away were broken.
The quantities released: 70 t of hydrocarbon and 0.3 t of hydrogen.
A different source assesses the total damage to 770 M$ corresponding to 879 M$ of 2021. Unclear how this was calculated.

Event Nature

Release type
Gas-liquid mixture
Involved substances (% vol)
H2,
naphta
Actual pressure (MPa)
2.5
Presumed ignition source
Not reported
Deflagration
Yes, cloud formation
Flame type
cloud

References

Reference & weblink

MARSH report, 100 largest losses in the hydrocarbon industry, 27th edition 2022<br />
https://www.marsh.com/cz/en/industries/energy-and-power/insights/100-la… />
(accessed January 2024)

From European database eMARS <br />
https://emars.jrc.ec.europa.eu/en/emars/accident/view/848b91b1-b27d-11e… />
(accessed December 2020)

NordBayern news of 28 November 2018:<br />
https://www.nordbayern.de/region/reaktor-riss-schuld-an-bayernoil-explo… />
(accessed January 2024)

Donaukurier video:<br />
https://www.youtube.com/watch?v=XXbByxpY8wc<br />
(accessed Janury 2024)

JRC assessment