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Clean Hydrogen Partnership

Hydrocarbons fire in a refiner

Event

Event ID
987
Quality
Description
During a work tour on a refinery, an employee noticed a fire at the level of a flange at the inlet of the grille of an exchanger, located at the outlet of a reactor of the catalytic reforming unit.

The plant operator detected a lack of uniformity of torque on the bolts. Two years before, during a shutdown period, some parts of the exchanger had been removed for inspection. The flange on the heat exchanger side was not easily accessible. During reassembly, the presence of a pipe tee near the flange made it difficult to tighten with a bolting machine. The faulty tightening (1.5 mm opening) could have led to the leakage of high-octane gasoline, mixed with hydrocarbon gases and hydrogen. Without a hot spot nearby, this 500°C fluid could have spontaneously ignited on contact with air.
The plant operator tightened the flange and modified procedures to specify the use of a suitable wrench for the configuration. The operator also planned to carry out independent checks on the quality of the connections made.
(ARIA database)
Event Initiating system
Classification of the physical effects
Hydrogen Release and Ignition
Nature of the consequences
Fire (No additional details provided)
Macro-region
Europe
Country
France
Date
Main component involved?
Flange
How was it involved?
Leak & Formation Of A Flammable H2-Hc-Air Mixture
Initiating cause
Loss Of Tightness (Wrong Operation)
Root causes
Root CAUSE analysis
The INITIATING cause was the ignition of leaked mixture of hydrocarbons, including hydrogen. The INTERMEDIATE or ROOT CAUSE could have been the lack of tightness of a flange caused by a not-properly tightening of the bolts. Finally, A CONTRIBUTING or ROOT CAUSE was the difficulty of re-assembling of the system due to design.

Facility

Application
Petrochemical Industry
Sub-application
catalytic reforming process
Hydrogen supply chain stage
All components affected
reformer, heat exchanger, flanges, bolts
Location type
Unknown
Location description
Industrial Area
Operational condition

Emergency & Consequences

Number of injured persons
0
Number of fatalities
0

Lesson Learnt

Lesson Learnt

The quality of the event description does not allow for a detailed lesson learnt. nevertheless, better operative/maintenance procedures and a (better) reporting system shall be part of it.
Corrective Measures
The plant operator modified procedures to specify the use of a suitable wrench for the configuration.
The operator also planned to carry out independent checks on the quality of the connections made.

Event Nature

Release type
gas mixture
Involved substances (% vol)
gasoline,
hydrocarbons,
H2
Presumed ignition source
Auto-ignition

References

Reference & weblink

Event description no 55225 in the French database ARIA <br />
https://www.aria.developpement-durable.gouv.fr/accident/55225_en/?lang=… />
(accessed October 2021)

JRC assessment