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Clean Hydrogen Partnership

Liquid hydrogen release from a truck

Event

Event ID
943
Quality
Description
The leak occurred on a 44 m³ vehicle of liquid hydrogen during a delivery to the unloading station of a steel plant. The truck drivers had connected the tank container to the fixed storage managed by a subcontractor, carried out a nitrogen sweep of the hose before cooling it, and were pressurizing the hydrogen before unloading when they saw a white cloud.

The drivers closed the bottom valve of the container and the upstream and downstream valves of the heater before evacuating the area and sounding the alarm.

Two technicians of the subcontractor company arrived 30 minutes later, located the leak on the flange of one of the four protective valves of the tank container. Two of the four fixing bolts were missing from the leaking flange.
The technicians closed the three ways valve which allowed to isolate the valves 2 by 2. They could then re-seale the flange
correctly and performe a leak test.
Event Initiating system
Classification of the physical effects
Unignited Hydrogen Release
Nature of the consequences
Leak No Ignition (No additional details provided)
Macro-region
Europe
Country
France
Date
Main component involved?
Flange (Cryogenic)
How was it involved?
Leak & Formation Of A Flammable H2-Air Mixture
Initiating cause
Wrong Installation
Root causes
Root CAUSE analysis
The INITIATING cause was the lack of tightness of a cryogenic tank flange, which started releasing when raising the transfer pressure.

The ROOT CAUSE was inadequate reassembling of some of the flange bolts during the previous maintenance, performed 17 days before.

Facility

Application
Hydrogen Transport And Distribution
Sub-application
LH2 tanker
Hydrogen supply chain stage
Hydrogen Transfer (No additional details provided)
All components affected
liquid hydrogen cryogenic tank, truck, liquid hydrogen heater
Location type
Open
Location description
Industrial Area
Operational condition
Pre-event occurrences
The tank drivers had started the procedure for unloading and evaporating the liquid hydrogen.

Description of the facility/unit/process/substances
DESCRIPTION OF THE PROCESS
This process consisted in:
1) connecting the tank container to the fixed storage
2) execute a nitrogen sweep of the hose and cooling it,
3) pressurizing the H2 before unloading.

The tank had a volume of 44 m3 corresponding to approximately 3200 kg of liquid hydrogen at full load.
The customer was a steel manufacturer.

Emergency & Consequences

Number of injured persons
0
Number of fatalities
0
Post-event summary
F

Lesson Learnt

Lesson Learnt
The ARIA report (see references) does not mention any corrective action, and also the real cause of the lack of tightness of the leaking flange is not identified.


There could be three non-exclusive root causes:
(1) Rad vibration which could loosen the bold.
(2) a human cause, because the maintenance procedure or the checks before tank delivery were not followed.
(3) an inadequate procedure, which (for example) does not foresees even a leak test under pressure after the maintenance, and/or a confinement integrity check before starting the hydrogen transfer .

In the first case, personnel training is required, in the second, a review of the procedure is required, probably assessed by a new risk assessment.

Event Nature

Release type
gas
Involved substances (% vol)
H2 100%
Released amount
0.7 kg
Actual pressure (MPa)
1
Design pressure (MPa)
1
Presumed ignition source
No ignition

References

Reference & weblink

Event description in the French database ARIA<br />
https://www.aria.developpement-durable.gouv.fr/accident/40965/<br />
(accessed October 2020)<br />

News of the event in Ouest France, 20/09/2011<br />
https://nantes.maville.com/actu/actudet_-une-fuite-d-hydrogene-vite-mai… />
(accessed October 2020)

JRC assessment