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Clean Hydrogen Partnership

Explosion in an electrolytic coating facility

Event

Event ID
896
Quality
Description
The explosion occurred in a copper electroplating plant test furnace when starting the operation of copper plating.

A tinned copper pipe had been placed inside another copper pipe and lined with pellets. Inside the furnace, the pellets were intended to adhere to the outer surface of the smaller tinned copper pipe under hydrogen atmosphere. The test was the third in the series. A vacuum was created inside the furnace, and an indicator light showed that a vacuum had been successfully generated. After 10 minutes from start, the furnace was switched to automatic operation and the employee exited the hall. The intention was to supply hydrogen to the furnace while it was on automatic operation. However, after 25 minutes, the furnace exploded.
Event Initiating system
Classification of the physical effects
Hydrogen Release and Ignition
Nature of the consequences
Macro-region
Europe
Country
Germany
Date
Root causes
Root CAUSE analysis
INITIATING cause was the inlet of air in a furnace filled with hydrogen, which ignited when switching on the heating of the graphite rods.

The furnace was equipped with two bleeding valves, one of which was manual and the other electronically operated by a pushbutton. The pushbutton-operated bleeding valve located in the vacuum under the furnace had remained in the open position when operation was commenced. However, the vacuum suction automation system kept the afore-mentioned valve closed during the period required for reaching the vacuum and the waiting period (5–7 min) following full vacuum. After that, hydrogen was introduced to the furnace automatically for about 10 min. After the purging gas valve had closed, the automation system no longer prevented the bleeding valve from opening; instead, air was allowed to pass to inside the furnace because the bleeding valve button was in the depressed position. The furnace was equipped with graphite rod elements that very quickly heat up the furnace to the set temperature. When the power supply switched on, the rods became quickly glowing red and ignited the hydrogen-air mixture. The hydrogen-air mixture inside the furnace exploded, the blind flanges of the furnace were dislocated out of their joints, and a pressure wave was propagated to the testing hall where no people were present at the time.
The cause of the explosion was the pushbutton-operated bleeding valve that had remained in the open position, which the signal lamp failed to indicate because it was broken. As a result, air found its way into the furnace through the said valve after the hydrogen valve had closed and the ‘waiting period’ was up, i.e. when the bleeding valve was no longer controlled by programmed automation.

ROOT CAUSE is not reported, nevertheless, however it can be deduced from the event description that it was related to a wrong automatic process design and perhaps as well to inadequate risk assessment..

Facility

Application
Steel And Metals Industry
Sub-application
copper plating
Hydrogen supply chain stage
All components affected
electrolytic coating plant, cupper plating process furnace
Location type
Confined
Location description
Industrial Area
Operational condition
Pre-event occurrences
It seems that the event occurred when using the furnace for testing electroplating methods. The intention was to supply hydrogen to the furnace while it was on automatic operation.

It is uncertaint if the actions which brought to theincident belonged to normal operations, or were a complere new set of expriemtns. It seems more probable the former option.

Emergency & Consequences

Number of injured persons
0
Number of fatalities
0
Environmental damage
0
Currency
Euro
Property loss (onsite)
2000000
Post-event summary
The explosion caused the doors at both ends of the hall bulging considerably outwards. Some of the fluorescent lighting tubes in the ceiling and their support frames fell down, while in some areas only the lighting tubes fell off.
The ceiling construction was lifted up by 2–3 cm.
The force of the pressure exerted on the actual furnace caused an oval deformation of approximately 20 mm and damaged its internals.

Lesson Learnt

Lesson Learnt

The lesson learnt is unknown, however there had been already several fire and explosion affection the electrical installation of this facility, a sign of bad facility and/or process design and poor risk assessment.

Event Nature

Release type
gas
Involved substances (% vol)
H2 100%
Presumed ignition source
Hot surface
Ignition delay
1500
High pressure explosion
Y

References

Reference & weblink

Event as described in the European eMARS database

HSE reporting a confidential report

Event from German database ZEMA<br />
https://www.infosis.uba.de/index.php/de/site/2854/zema/index/3325.html<… />
(accessed December 2024)

JRC assessment