Event
- Event ID
- 842
- Quality
- Description
- A deflagration occurred at a chemical plant during a synthesis operation involving sodium tri-acetoxy-borohydride inside a 5,300-litre reactor.
Around 5:30 pm, the technician observed that the acetic acid intake pipe was blocked. After opening the manhole with a wooden pole, the shop foreman dropped the stalactite of solidified acetic acid in the reactor: the resulting blast severely burned the foreman’s face.
The event was caused by ignition of the hydrogen produced from the dropped quantity of acetic acid. The maximum amount of acetic acid introduced into the reactor was estimated by the operator at 3 kg, and it led to the formation of approx. 100 grams of hydrogen in this 5,300-liter reactor.
The accident had no impact either on the environment or on other shop installations. - Event Initiating system
- Classification of the physical effects
- Hydrogen Release and Ignition
- Nature of the consequences
- Macro-region
- Europe
- Country
- France
- Date
- Root causes
- Root CAUSE analysis
- The INITIATING cause of the blast was the manual operation in the chemical reactor, which brought a person direction in contact with the substances in the reactor.
Facility
- Application
- Chemical Industry
- Sub-application
- Inorganic chemicals products
- Hydrogen supply chain stage
- All components affected
- reactor dedicated to acetic acid, sodium tri-acetoxy-borohydride
- Location type
- Confined
- Location description
- Industrial Area
- Operational condition
- Description of the facility/unit/process/substances
- DESCRIPTION OF THE PROCESS
Sodium triacetoxyborohydride, also known as sodium triacetoxyhydroborate, commonly abbreviated STAB, is a chemical compound with the formula Na(CH3COO)3BH. Like other borohydrides, it is used as a reducing agent in organic synthesis (Wikipedia).
Emergency & Consequences
- Number of injured persons
- 1
- Number of fatalities
- 0
- Post-event summary
- Blast severely burned the foreman’s face.
The accident had no impact either on the environment or on other shop installations.
Event Nature
- Release type
- gas
- Involved substances (% vol)
- H2 100%
- Released amount
- 0.1 kg (H2)
- Presumed ignition source
- Static electricity
- Deflagration
- Y
References
- Reference & weblink
ARIA data base <br />
event no. 34921
JRC assessment
- Sources categories
- ARIA