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Clean Hydrogen Partnership

Hydrogen & hydrocarbon fire in the desulphurization unit of a refinery

Event

Event ID
841
Quality
Description
The leak ignited at the seal located between the bottom and the body of a heat exchanger of a desulphurization unit of a refinery.
The fire is alimented by the leaking fuel under pressure for about twenty minutes causing the emission of a plume of black smoke. The operation of decompression of the unit is delayed by the malfunction of an automated system. Nevertheless, when finally successful, it allows the fire to be controlled and then completely extinguished after emptying the reactor located upstream (morning of the following day).
The intervention is provided by the emergency services of the operator without recourse to the firefighters of the municipality put however on preventive alert.
The affected unit was stopped, repaired and restarted only 4 weeks later.
The analysis of the causes performed by the operator reveals a failure of the mounted seal, different from the seal recommended at this point, poorly positioned and tightened non-homogeneously.
Event Initiating system
Classification of the physical effects
Hydrogen Release and Ignition
Nature of the consequences
Fire (No additional details provided)
Macro-region
Europe
Country
France
Date
Root causes
Root CAUSE analysis
The INITIATING CAUSE of the release was the failure of the seal.
The ROOT CAUSE was a mistake when mounting the seal, which was different from the recommended seal, poorly positioned and tightened non-homogeneously.

Facility

Application
Petrochemical Industry
Sub-application
Hydrodesulphurisation process
Hydrogen supply chain stage
All components affected
heat exchanger of a desulphurization unit, refinery
Location type
Open
Location description
Industrial Area
Operational condition

Emergency & Consequences

Number of injured persons
0
Number of fatalities
0
Post-event summary
The unit was restarted only 4 weeks later.

Event Nature

Release type
gas mixture
Involved substances (% vol)
H2
hydrocarbons
Presumed ignition source
Not reported

References

Reference & weblink

ARIA data base <br />
event no. 32145

JRC assessment