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Clean Hydrogen Partnership

Explosion in a facility for boilers maintenance

Event

Event ID
838
Quality
Description
The explosion occurred during repair work on a boiler. A technician had previously descaled the device using hydrochloric acid, after which he performed the neutralisation step with soda and drained the passivated acid.
The significant scaling on the boiler required a second acid injection, followed by welding work, but this time the rest of the acid had not been drained from the boiler.
Hydrogen emitted by a metal + acid reaction was the cause of this accident. An employee wound up in hospital in a coma.
Labour inspection authorities noted that operating conditions were not respecting environmental protection requirements, i.e. failure to control discharge pH.
They also noted the absence of written procedures.
Event Initiating system
Classification of the physical effects
Hydrogen Release and Ignition
Nature of the consequences
Macro-region
Europe
Country
France
Date
Root causes
Root CAUSE analysis
INITIATING cause was failure to perform an operative step
This caused the formation of hydrogen from the reaction of hydrochloric acid with metals, in presence of a hot source (welding).
Root cause (probably) found to be the absence of any written procedure.

Facility

Application
Other
Sub-application
Boilers industry
Hydrogen supply chain stage
All components affected
Workshop for maintenance of boilers, hydochloric acid
Location type
Confined
Operational condition
Pre-event occurrences
The explosion occurred during repair work on a boiler.

Emergency & Consequences

Number of injured persons
1
Number of fatalities
0
Post-event summary
An employee wound, in hospital in a coma.
Official legal action
Labour inspection authorities noted that operating conditions were not favourable towards environmental protection, i.e. failure to control discharge pH, absence of written procedures.

Event Nature

Release type
Gas-liquid-solid mixture
Involved substances (% vol)
NaHO,
metals,
H2
Presumed ignition source
Welding

References

Reference & weblink

ARIA data base <br />
event no. 28569

JRC assessment