Event
- Event ID
- 663
- Quality
- Description
- An explosion occurred in a nitrogen wash cold box (outside the equipment) after a several day cold shutdown followed by a derime with nitrogen. It is assumed that ice may have split tubes permitting carbon monoxide and hydrogen to leak into the perlite installation. It is likewise assumed that the insulation had channelled and had many voids.
However, the insulation was continuously purged with nitrogen and the mechanism of the explosion is still unknown. - Event Initiating system
- Classification of the physical effects
- Hydrogen Release and Ignition
- Nature of the consequences
- Macro-region
- North America
- Country
- United States
- Date
- Main component involved?
- Pipe (Weld)
- How was it involved?
- Rupture & Formation Of A Flammable H2-Hc-Air Mixture
- Initiating cause
- Material Degradation (Generic)
- Root causes
- Root CAUSE analysis
- The INITIATING CAUSE were cracks in aluminium welds which leaked hydrogen cumulating in the cold box.
A CONTRIBUTING FACTOR was the cold weather which could have caused the formation of ice. Since the cold box thermal insulation, consisting of perlite, was purged with nitrogen, it is unclear why hydrogen and CO could form an explosive atmosphere.
The ROOT CAUSE is not provided. It could nevertheless plausibly attributed to design and/or manufacturing (welding) error.
Facility
- Application
- Chemical Industry
- Sub-application
- cryogenic separation of H2 feed gas
- Hydrogen supply chain stage
- All components affected
- cold box
- Location type
- Unknown
- Operational condition
- Description of the facility/unit/process/substances
- DECRITION OF THE PROCESS
A "derime" is a maintenance procedure used to remove frozen impurities from a cryogenic system, such as a nitrogen or air separation unit. This is done by warming up the equipment and flowing a warm, dry gas through it to melt and purge any accumulated moisture, carbon dioxide, or other contaminants that would otherwise freeze and block the system. The terms "derime," "defrost," "de-ice," and "thaw" are often used interchangeably for this process.
Emergency & Consequences
- Number of injured persons
- 0
- Number of fatalities
- 0
- Environmental damage
- 0
- Currency
- US$
- Property loss (onsite)
- 1900000
Event Nature
- Release type
- gas mixture
- Involved substances (% vol)
- H2
CO - Release duration
- unknown
- Presumed ignition source
- Static electricity
References
- Reference & weblink
Event description extracted from the UK database ICHEME in PDF.<br />
The <br />
https://www.icheme.org/knowledge/safety-centre/resources/accident-data/ <br />
(accessed October 2020)Table III of Appendix A of Zalosh and Short<br />
COMPARATIVE ANALYSIS OF HYDROGEN FIRE AND EXPLOSION INCIDENTS<br />
Quarterly Report No. 2 for Period December 1, 1977 - February 28, 1978<br />
https://www.osti.gov/biblio/6566131<br />
(accessed September 2020)LOSS PREVENTION, VOL. 3.
JRC assessment
- Sources categories
- ICHEME