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Clean Hydrogen Partnership

Hydrogen leak from a cold box

Event

Event ID
662
Quality
Description
A hydrogen leak occurred in a CO (carbon monoxide) - hydrogen separation cold box of an acetic acid plant.
Event Initiating system
Classification of the physical effects
Unignited Hydrogen Release
Nature of the consequences
Leak No Ignition (No additional details provided)
Macro-region
North America
Country
United States
Date
Main component involved?
Heat Exchanger
How was it involved?
Leak & Formation Of A Flammable H2-Air Mixture
Initiating cause
Unknown
Root causes
Unknown (No additional details provided)

Facility

Application
Chemical Industry
Sub-application
acetic acid plant
Hydrogen supply chain stage
All components affected
Separation equipment
Location type
Unknown
Operational condition
Unknown (No additional details provided)
Description of the facility/unit/process/substances
DESCRIPTION OF THE UNIT
A CO-hydrogen separation cold box is an insulated steel structure that houses cryogenic equipment used to separate carbon monoxide (CO) and hydrogen (H2) from a gas mixture based on their different boiling points. It operates at very low temperatures to partially condense and then distill the components, achieving high purity separation of the CO and H2 products. 

DESCRIPTION OF THE PROCESS
The process adopted in this plant was probably the methanol carbonylation, where methanol and CO reacts in presence of a catalyst.

Emergency & Consequences

Number of injured persons
0
Number of fatalities
0

Event Nature

Release type
gas
Involved substances (% vol)
H2 100%
Presumed ignition source
No ignition

References

Reference & weblink

Marsh Rerports 100 LARGEST LOSSES

JRC assessment