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Clean Hydrogen Partnership

unintended hydrogen formation from metallic powder

Event

Event ID
640
Quality
Description
Fire of drums containing lithium metal powder: Spontaneous combustion took place at drums containing lithium metal powder which were charged with argon gas for experiments. While lithium metal powder had usually been kept inside films of fluid paraffin to avoid its contact with water, it was stored in drums charged with argon gas for reuse in a tentative way. Water in the air got in to react with lithium because of incomplete sealing of the drums. In addition, the reaction heat built up under hot and humid condition on the day of accident leading to ignition of hydrogen or lithium.
Event Initiating system
Classification of the physical effects
Hydrogen Release and Ignition
Nature of the consequences
Fire (No additional details provided)
Macro-region
Asia
Country
Japan
Date
Root causes
Root CAUSE analysis
The ROOT CAUSE seems a combination of (i) a human error, when Li was stored 'by tentative way' stored differently from the usual procedure, and a lack of inspection/maintenance, due to the fact that that the drum was leaking. Unknown is the role of supervisors/ management.

Facility

Application
Steel And Metals Industry
Sub-application
lithium production
Hydrogen supply chain stage
All components affected
lithium powders,
Location type
Unknown
Location description
Industrial Area
Operational condition
Pre-event occurrences
An experimental operation was attempted

Emergency & Consequences

Number of injured persons
0
Number of fatalities
0

Event Nature

Release type
gas-solid mixture
Involved substances (% vol)
H2,
lithium
Presumed ignition source
Not reported

References

Reference & weblink

Orignal source lost. RISCAD is closed.

JRC assessment