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Clean Hydrogen Partnership

Explosion at the off-gas system of a nuclear power plant

Event

Event ID
627
Quality
Description
During steady-state operations an explosion occurred in the off-gas system.

[Zalosh and Short, 1978]
Event Initiating system
Classification of the physical effects
Hydrogen Release and Ignition
Nature of the consequences
Macro-region
North America
Country
United States
Date
Main component involved?
Off-Gas System
How was it involved?
Internal Explosion (H2-O2 Mixture)
Initiating cause
Unknown
Root causes
Unknown (No additional details provided)

Facility

Application
Power Plant
Sub-application
Nuclear power plant - BWR
Hydrogen supply chain stage
Location type
Confined
Location description
Industrial Area
Operational condition
Description of the facility/unit/process/substances
DESCRIPTION OF THE OFF-GAS SYSTEM OF BWR
Historically, off-gas treatment consisted in:
(1) dilution of the stoichiometric hydrogen-oxygen mixture with steam or air.
(2) Recombination and removal of the water/moisture.
(3) Reduction of the radioactivity of the of the noble gases, by passing the gas through a charcoal bed or delay pipes.
(4) Abatement of the radioactive decay products in the stream by flowing the gas through a high-efficiency filter particulate to remove,
(5) venting the gas to the atmosphere through an elevated stack.
Older BWR power plants may be missing all but (5).

Emergency & Consequences

Number of injured persons
0
Number of fatalities
0
Currency
US$

Lesson Learnt

Lesson Learnt
Hydrogen and oxygen are generated in a nuclear reactor by radiolysis of steam in the cooling system. If not properly extracted and handled, the two gases can build up a flammable mixture which can explode. Therefore, when the steam is condensed, the off-gases are extracted into an off-gas treatment system. Throughout the year 1960-80, explosions have been reported in various components of off-gas systems.

Zalosh and Short included in their report (“Comparative analysis of hydrogen fire and explosion incidents”, see references) 25 incidents of this type happened in the US in the 1966-77 period, caused by formation of flammable hydrogen-oxygen mixtures in cooling loops of boiling-water-reactor (BWR) nuclear power plants. A selection of them appears also in HIAD.
Despite the occurrences, equipment damage has been minimal in most of the off-gas explosions, probably because the Regulator required the system upstream of the recombiner to be designed to withstand hydrogen-oxygen explosions.
Most of the related injuries were due exposure to radioactive gases. Since the gases were usually short-lived radionuclides, contaminated workers recovered rapidly, i.e., within a day or two.
Corrective Measures
See incident HIAD_499 for the lesson learnt and related corrective measures following the occurrence of this type of incidents in the years 70’s , occurring in the off-gas system of BWR’s.

Event Nature

Release type
gas mixture
Involved substances (% vol)
H2,
O2
Ignition delay
Not reported

References

Reference & weblink

Table II - Industrial Incidents of Appendix A of Zalosh and Short<br />
COMPARATIVE ANALYSIS OF HYDROGEN FIRE AND EXPLOSION INCIDENTS<br />
Quarterly Report No. 2 for Period December 1, 1977 - February 28, 1978<br />
https://www.osti.gov/biblio/6566131<br />
(accessed September 2020)

JRC assessment