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Clean Hydrogen Partnership

Explosion at a sodium chlorate production unit

Event

Event ID
585
Quality
Description
A lack of nitrogen purge in empty electrolytic chlorate cells allowed hydrogen to accumulate and to form a hydrogen-chlorine explosive mixture.

[Zalosh and Short, 1978]
Event Initiating system
Classification of the physical effects
Hydrogen Release and Ignition
Nature of the consequences
Macro-region
North America
Country
United States
Date
Main component involved?
Electrolytic Cell
How was it involved?
Internal Explosion H2-Cl2 Mixture)
Initiating cause
Inadequate Or No Purge
Root causes
Unknown (No additional details provided)

Facility

Application
Chemical Industry
Sub-application
sodium chlorite production
Hydrogen supply chain stage
Location type
Confined
Location description
Unknown
Operational condition
Unknown (No additional details provided)
Description of the facility/unit/process/substances
DESCRIPTION OF THE PROCESS
“Sodium chlorate is an inorganic compound produced by the electrolysis of concentrated sodium chloride solutions (NaCl).
The overall reaction can be simplified to the equation:
NaCl + 3 H2O → NaClO3 + 3 H2

[https://en.wikipedia.org/wiki/Sodium_chlorate]

Emergency & Consequences

Number of injured persons
1
Number of fatalities
0
Currency
US$
Property loss (onsite)
7000

Event Nature

Ignition delay
Static electricity

References

Reference & weblink

Table II - Industrial Incidetns of Appendix A of Zalosh and Short<br />
COMPARATIVE ANALYSIS OF HYDROGEN FIRE AND EXPLOSION INCIDENTS<br />
Quarterly Report No. 2 for Period December 1, 1977 - February 28, 1978<br />
https://www.osti.gov/biblio/6566131<br />
(accessed September 2020)

JRC assessment