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Clean Hydrogen Partnership

Explosion in a chlorine production plan.

Event

Event ID
488
Quality
Description
The vent occurred a chlorine electrolyser using mercury amalgam. Hydrogen entered the chlorine header and igniting spontaneously causing explosion. It did not vent properly, and the hydrogen analyzer was provided but not used.

[Zalosh and Short, 1978]
Event Initiating system
Classification of the physical effects
Hydrogen Release and Ignition
Nature of the consequences
Macro-region
North America
Country
United States
Date
Main component involved?
Electrolytic Cell
How was it involved?
Internal Explosion (H2-Air Mixture)
Initiating cause
Malfunctioning (Electrolyser, Cross-Over)
Root causes
Root CAUSE analysis
The fact that a hydrogen analyser was available but not used suggests an inadequate control of the process, which may have its root in a failure to follow procedures, and/or failure in management of hazards.

Facility

Application
Chemical Industry
Sub-application
chlorine production
Hydrogen supply chain stage
Location type
Confined
Location description
Unknown
Operational condition

Emergency & Consequences

Number of injured persons
0
Number of fatalities
0
Currency
US$
Property loss (onsite)
2500

Event Nature

Release type
gas mixture
Involved substances (% vol)
H2,
Cl2
Ignition delay
Auto-ignition

References

Reference & weblink

Table II - Industrial Incidents of Appendix A of Zalosh and Short<br />
COMPARATIVE ANALYSIS OF HYDROGEN FIRE AND EXPLOSION INCIDENTS<br />
Quarterly Report No. 2 for Period December 1, 1977 - February 28, 1978<br />
https://www.osti.gov/biblio/6566131<br />
(accessed September 2020)

JRC assessment