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Clean Hydrogen Partnership

Explosion in a trays cleaning unit

Event

Event ID
312
Quality
Description
A wash machine was being used to clean aluminium trays with burnt on product. The auto wash in normal situations cleaned steel trays, and not aluminium. The cleaning fluid contained sodium hydroxide (NaOH). When it entered in contact with the cleaning fluid a "froth" formed in the wash tub, accompanied with hydrogen gas.

A cleaning worker was requested to clean up the froth, and used a wet vacuum cleaner. This cleaner seemingly also removed the hydrogen element with the froth, which in turn ignited due to sparking from the vacuum cleaner motor.
Event Initiating system
Classification of the physical effects
Hydrogen Release and Ignition
Nature of the consequences
Macro-region
Europe
Country
United Kingdom
Date
Main component involved?
Vacuum Cleaner
How was it involved?
Internal Explosion (H2-Air Mixture)
Initiating cause
Run-Away Reaction
Root causes
Root CAUSE analysis
The INITIATING CAUSE was the accidental formation of hydrogen when washing aluminium tray with sodium hydroxide.

There was a lack of understanding of the cleaning product used and its applications, as COSHH sheets on this product, available on site, explicitly stated that this product was not to be used on aluminium.

The ROOT CAUSE is failure to understand and apply procedures.

Facility

Application
Other
Sub-application
Industrial cleaner
Hydrogen supply chain stage
All components affected
Industrial vacuum cleaner
Location type
Unknown
Location description
Industrial Area
Operational condition

Emergency & Consequences

Number of injured persons
1
Number of fatalities
0
Post-event summary
The cleaner was uninjured but took time off due to shock, which resulted in the incident being reported.

Lesson Learnt

Lesson Learnt
This incident is an example of a low-technology industrial process where things went wrong when something was changed to the process. The process had been designed for washing used for steel parts. When washing aluminium parts, the cleaning fluid behaved differently. In absence of an extensive knowledge of the ongoing chemical process, operators try usually to remediate to the unexpected results with what is available onsite.

However, to avoid the incident would hace been enough to read the safety sheets held by the company, which specifically stated not to use on Aluminium. There waas a lack of understanding and availability of this information on behalf of manager.
Nevertheless, the investigation conclusions were that

Event Nature

Release type
gas
Involved substances (% vol)
H2 100%
Presumed ignition source
Electricity
Deflagration
N
High pressure explosion
N
High voltage explosion
N

References

Reference & weblink

Event description provided by HSE, original source confidential

JRC assessment