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Clean Hydrogen Partnership

Explosion of hydrogen and gas oil with subsequent fire at a refinery

Event

Event ID
50
Quality
Description
The incident occurred at a heat exchanger involving gas-product mixture. The source does not specify the process, with as main component a furnace, probably a hydrodesulphurisation reactor. Due to a leak in the pipe, the mixture was released and formed a vapour cloud. Following ignition, a fire developed at the leaking point.
The plant fire brigade was alerted and laid a foam carpet over the entire area. The furnace system, the as circulation compressor and the injection pump were switched off in an emergency. The emergency expansion valve was opened and nitrogen was fed into the circuit.
No injuries, only equipment damage.
Event Initiating system
Classification of the physical effects
Hydrogen Release and Ignition
Nature of the consequences
Macro-region
Europe
Country
Germany
Date
Main component involved?
Heat Exchanger (Pipe)
How was it involved?
Leak & Formation Of A Flammable H2-Hc-Air Mixture
Root causes
Unknown (No additional details provided)
Root CAUSE analysis
A material failure was suspected to as INITIATING CAUSE of the leak. Nothing is known on the operative aspects of the event.

Facility

Application
Petrochemical Industry
Sub-application
unspecified
Hydrogen supply chain stage
All components affected
pipe, heat exchangeer
Location type
Unknown
Location description
Industrial Area
Operational condition

Emergency & Consequences

Number of injured persons
0
Number of fatalities
0
Environmental damage
0
Currency
Euro
Property loss (onsite)
500000
Property loss (offsite)
0
Post-event summary
There were no personal injuries. The property damage due to partial destruction of equipment as a result of the fire amounted to 500,000 euros. There was no environmental damage.
Emergency action
The fire was limited to the vicinity of the ruptured reactor and was extinguished within twenty minutes by onsite emergency services (four people).

After the accident, the plant was shut-down and the reactor purged. Its contents was removed and the reactor was prepared to open it to allow an internal examination.

Lesson Learnt

Corrective Measures

A revision and expansion of the wall thickness measuring programs, to be able to detect on time critical loos of resistance and percent loss of confinement.

Event Nature

Release type
gas mixture
Involved substances (% vol)
H2S 10 kg
H2 100 kg
Hydrocarbons 1200 kg
Presumed ignition source
Not reported

References

Reference & weblink

Event from German database ZEMA<br />
https://www.infosis.uba.de/index.php/de/site/12981/zema/index/2869.html… />
(accessed December 2023)

JRC assessment