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Clean Hydrogen Partnership

Fire in a zirconium production plant

Event

Event ID
37
Quality
Description
Due to the failure of a exhaust system, compressed hydrogen leaked into an area containing electrical components, with consequent fire.
Leakage was allowed when exhaust system failed.
Event Initiating system
Classification of the physical effects
Hydrogen Release and Ignition
Nature of the consequences
Fire (No additional details provided)
Macro-region
North America
Country
United States
Date
Main component involved?
Venting System (Stack)
How was it involved?
Leak & Formation Of A Flammable H2-Air Mixture
Initiating cause
Unknown
Root causes
Root CAUSE analysis
The INITIATING CAUSE was the failure of a exhaust vent, which caused hydrogen to access an indoor area with ignition source.

According to Zalosh’ report, when the venting system failed, ‘leakage was allowed’. If this means that the operator decided to execute anyhow a venting, taking into account the diffusion on hydrogen into the workshop, the ROOT CAUSE could be related to an inadequate management decision.
In addition, it could be also related to an inadequate risk assessment in the design phase, which did not consider this specific accidental scenario and therefore did not take the required mitigating measures.

Facility

Application
Steel And Metals Industry
Sub-application
zirconium production
Hydrogen supply chain stage
All components affected
zirconium production line, hydrogen exhaust system, electrical area
Location type
Unknown
Location description
Industrial Area
Operational condition

Emergency & Consequences

Number of injured persons
0
Number of fatalities
0
Environmental damage
0
Currency
US$
Property loss (onsite)
8000
Property loss (offsite)
0
Post-event summary
No injuries, 8000 $ material damage
Emergency action
A deflagration occurs following a hydrogen leak and its inflammation on a unit conditioning hydrogen. The fire is extinguished by the workers and hydrogen feeding is closed. The installation is stopped and placed under nitrogen.

Event Nature

Release type
gas
Involved substances (% vol)
H2 100%
Release duration
unknown
Presumed ignition source
Electricity
Flame type
Other

References

Reference & weblink

Table II of Appendix A of Zalosh and Short<br />
COMPARATIVE ANALYSIS OF HYDROGEN FIRE AND EXPLOSION INCIDENTS<br />
Quarterly Report No. 2 for Period December 1, 1977 - February 28, 1978<br />
https://www.osti.gov/biblio/6566131<br />
(accessed September 2020)

JRC assessment