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Clean Hydrogen Partnership

Fire in a process reactor of a chemical plant.

Event

Event ID
842
Quality
Description
A deflagration occurred at a chemical plant during a synthesis operation involving sodium tri-acetoxy-borohydride inside a 5,300-litre reactor.
Around 5:30 pm, the technician observed that the acetic acid intake pipe was blocked. After opening the manhole with a wooden pole, the shop foreman dropped the stalactite of solidified acetic acid in the reactor: the resulting blast severely burned the foreman’s face.
The event was caused by ignition of the hydrogen produced from the dropped quantity of acetic acid. The maximum amount of acetic acid introduced into the reactor was estimated by the operator at 3 kg, and it led to the formation of approx. 100 grams of hydrogen in this 5,300-liter reactor.
The accident had no impact either on the environment or on other shop installations.
Event Initiating system
Classification of the physical effects
Hydrogen Release and Ignition
Nature of the consequences
Macro-region
Europe
Country
France
Date
Root causes
Root CAUSE analysis
The INITIATING cause of the blast was the manual operation in the chemical reactor, which brought a person direction in contact with the substances in the reactor.

Facility

Application
Chemical Industry
Sub-application
Inorganic chemicals products
Hydrogen supply chain stage
All components affected
reactor dedicated to acetic acid, sodium tri-acetoxy-borohydride
Location type
Confined
Location description
Industrial Area
Operational condition
Description of the facility/unit/process/substances
DESCRIPTION OF THE PROCESS
Sodium triacetoxyborohydride, also known as sodium triacetoxyhydroborate, commonly abbreviated STAB, is a chemical compound with the formula Na(CH3COO)3BH. Like other borohydrides, it is used as a reducing agent in organic synthesis (Wikipedia).

Emergency & Consequences

Number of injured persons
1
Number of fatalities
0
Post-event summary
Blast severely burned the foreman’s face.
The accident had no impact either on the environment or on other shop installations.

Event Nature

Release type
gas
Involved substances (% vol)
H2 100%
Released amount
0.1 kg (H2)
Presumed ignition source
Static electricity
Deflagration
Y

References

Reference & weblink

ARIA data base <br />
event no. 34921

JRC assessment