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Clean Hydrogen Partnership

Fire in a fired heater of an ethylene plant

Event

Event ID
1169
Quality
Description
An explosion of a mixture of hydrogen and hydrocarbons occurred at a fired heater of a refinery.
A mixture of a hydrogen and hydrocarbon mixture was accidentally released into the firebox of a fired heater, where it ignited, creating a large fire at a refinery.
The fired heater that had been offline for approximately 12 hours due to an unplanned compressor shutdown. During the start-up, after the burners were ignited, the process fluid failed to flow in all four passes. This caused the tube wall temperature to reach 1500 F (815 C), exceeding the design limit. The operator turned out two of the 8 burners and reduced the flow throw the first 3 passes, to help the flow in the forth. An inspection team found the tubes gluing red, but thought to hear the flow in the fourth passes, concluding that the flow meter, which was giving no flow, was malfunctioning,
After less than a hour later, a tube in the fourth pass ruptured due to overheating), releasing 1800 kg of a mixture of hydrogen and hydrocarbons into the firebox. The mixture was ignited by the burners producing a large fire.
No injuries, estimated that the property damage from the incident was $10 million.
Event Initiating system
Classification of the physical effects
Hydrogen Release and Ignition
Nature of the consequences
Macro-region
North America
Country
United States
Date
Main component involved?
Heat Exchanger (Pipe)
How was it involved?
Rupture
Initiating cause
Over-Heating
Root causes
Root CAUSE analysis
The INITIATING CAUSE was due to lack of flow in one of the fired heater passes, which caused the loss of confinement of one of the tube due to over-heating.
The IGNITION was provide by the burners flames
CONTRIBUTION and ROOT CAUSES were:
(i) the correct start-up procedure was not followed. This procedure required maintaining a steady flow through all four tube-passes before lighting the burners.
(ii) the fired heater lacked engineered safeguards to prevent the burners from being lit before establishing flow in each of the four passes.

Facility

Application
Petrochemical Industry
Sub-application
Refinery
Hydrogen supply chain stage
All components affected
heater tube, fire box, fired heater
Location type
Confined
Location description
Industrial Area
Operational condition
Pre-event occurrences
The fired heater that had been offline for approximately 12 hours due to an unplanned compressor shutdown.

Emergency & Consequences

Number of injured persons
0
Number of fatalities
0
Currency
US$
Property loss (onsite)
10000000

Lesson Learnt

Lesson Learnt

An automated safeguard would have prevented the burners from being ignited before the minimum flow was established through each of the four tube passes contributed to the incident. The fact that such a system was not present hint at a lack of realistic accidental scenarios supporting a correct risk assessment.

Corrective Measures

In response to the incident, the company modified its automated burner controls to ensure that the flow rate through every pass exceeded a predetermined minimum flow rate before operators could ignite a burner.

Event Nature

Release type
gas mixture
Involved substances (% vol)
H2, hydrocarbon
Released amount
1800 kg
Presumed ignition source
Open flame

References

Reference & weblink

CBS incident reports volume 2<br />
https://www.csb.gov/us-chemical-safety-board-releases-volume-2-of-chemi… />
accessed April 2025

JRC assessment