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Clean Hydrogen Partnership

Fire in a chemical plant

Event

Event ID
212
Quality
Description
The fire developed on one of two naphtha crackers for the production of ethylene.
The rupture of the reactor made that the hydrogen, petroleum products (benzene) and the pyrophoric catalyst came outside the reactor. The mixture immediately caught fire in the air. The fire was brief but intense.
The fire reduced ethylene production by 40% for two weeks.
The release species were: benzene: 12 tonnes; hydrogen: amount unknown; catalyst : amount unknown.
Event Initiating system
Classification of the physical effects
Hydrogen Release and Ignition
Nature of the consequences
Fire (No additional details provided)
Macro-region
Europe
Country
Netherlands
Date
Main component involved?
Reactor / Oven / Furnace / Test Chamber
How was it involved?
Rupture & Formation Of A Flammable H2-Hc-Air Mixture
Initiating cause
Unknown
Root causes
Unknown (No additional details provided)

Facility

Application
Chemical Industry
Sub-application
naphta cracker
Hydrogen supply chain stage
All components affected
Reactor
Location type
Open
Location description
Industrial Area
Operational condition
Unknown (No additional details provided)

Emergency & Consequences

Number of injured persons
0
Number of fatalities
0
Currency
Euro
Property loss (onsite)
500000
Post-event summary
The damge costs is estimated based on eMARS and other sources
Emergency action
At 3:40 p.m. a worker on the spot noticed a leak in the structure behind the reactor and reported it to the control room. The operational staff who went to the location found white smoke leaking from the hydrogen supply line followed by the outbreak of a fire with a light-coloured, horizontal flame. The alarm was raised and the order given for the unit to be rapidly depressurised and cut off.
The firefighting team attended an air cooler where a fire was clearly breaking out and in the vicinity of the reactor using the necessary firefighting vehicles and equipment to contain the incipient fire and cool the surrounding metal structures.
The local fire brigade was called at 4:05 p.m. once it had become clear how serious the situation was. When the firefighters arrived, they continued the containment and cooling activities with the help of refinery personnel. Operations continued through the night until 7:50 a.m. on 2 December, with cooling and control activities going on until the afternoon of 2 December.
As per the IEP, the local authorities were kept constantly abreast of how the accident was developing, both by the company and by fire brigade representatives present on site. Based on how the situation developed, the local authorities did not deem it necessary to trigger the External Emergency Plan (EEP).

Event Nature

Release type
gas-solid mixture
Involved substances (% vol)
H2,
benzene 12 t,
catalyst
Released amount
12 t (benzene)
Presumed ignition source
Catalytic reaction

References

Reference & weblink

Event description in European database eMARS<br />
https://emars.jrc.ec.europa.eu/en/emars/accident/view/c8400204-63c9-e1f… />
(accessed September 2020)

Event description in French database ARIA<br />
https://www.aria.developpement-durable.gouv.fr/accident/22301/<br />
(accessed September 2020)

JRC assessment