Event
- Event ID
- 212
- Quality
- Description
- The fire developed on one of two naphtha crackers for the production of ethylene.
The rupture of the reactor made that the hydrogen, petroleum products (benzene) and the pyrophoric catalyst came outside the reactor. The mixture immediately caught fire in the air. The fire was brief but intense.
The fire reduced ethylene production by 40% for two weeks.
The release species were: benzene: 12 tonnes; hydrogen: amount unknown; catalyst : amount unknown. - Event Initiating system
- Classification of the physical effects
- Hydrogen Release and Ignition
- Nature of the consequences
- Fire (No additional details provided)
- Macro-region
- Europe
- Country
- Netherlands
- Date
- Main component involved?
- Reactor / Oven / Furnace / Test Chamber
- How was it involved?
- Rupture & Formation Of A Flammable H2-Hc-Air Mixture
- Initiating cause
- Unknown
- Root causes
- Unknown (No additional details provided)
Facility
- Application
- Chemical Industry
- Sub-application
- naphta cracker
- Hydrogen supply chain stage
- All components affected
- Reactor
- Location type
- Open
- Location description
- Industrial Area
- Operational condition
- Unknown (No additional details provided)
Emergency & Consequences
- Number of injured persons
- 0
- Number of fatalities
- 0
- Currency
- Euro
- Property loss (onsite)
- 500000
- Post-event summary
- The damge costs is estimated based on eMARS and other sources
- Emergency action
- At 3:40 p.m. a worker on the spot noticed a leak in the structure behind the reactor and reported it to the control room. The operational staff who went to the location found white smoke leaking from the hydrogen supply line followed by the outbreak of a fire with a light-coloured, horizontal flame. The alarm was raised and the order given for the unit to be rapidly depressurised and cut off.
The firefighting team attended an air cooler where a fire was clearly breaking out and in the vicinity of the reactor using the necessary firefighting vehicles and equipment to contain the incipient fire and cool the surrounding metal structures.
The local fire brigade was called at 4:05 p.m. once it had become clear how serious the situation was. When the firefighters arrived, they continued the containment and cooling activities with the help of refinery personnel. Operations continued through the night until 7:50 a.m. on 2 December, with cooling and control activities going on until the afternoon of 2 December.
As per the IEP, the local authorities were kept constantly abreast of how the accident was developing, both by the company and by fire brigade representatives present on site. Based on how the situation developed, the local authorities did not deem it necessary to trigger the External Emergency Plan (EEP).
Event Nature
- Release type
- gas-solid mixture
- Involved substances (% vol)
- H2,
benzene 12 t,
catalyst - Released amount
- 12 t (benzene)
- Presumed ignition source
- Catalytic reaction
References
- Reference & weblink
Event description in European database eMARS<br />
https://emars.jrc.ec.europa.eu/en/emars/accident/view/c8400204-63c9-e1f… />
(accessed September 2020)Event description in French database ARIA<br />
https://www.aria.developpement-durable.gouv.fr/accident/22301/<br />
(accessed September 2020)
JRC assessment
- Sources categories
- eMARS