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Clean Hydrogen Partnership

Explosion in a tungsten oxide ore refinery

Event

Event ID
484
Quality
Description
The explosion occurred in a furnace used for tungsten ore reduction, because hydrogen had not been vented completely.

[Zalosh and Short, 1978]
Event Initiating system
Classification of the physical effects
Hydrogen Release and Ignition
Nature of the consequences
Macro-region
North America
Country
United States
Date
Main component involved?
Reactor / Oven / Furnace / Test Chamber
How was it involved?
Internal Explosion (H2-Air Mixture)
Initiating cause
Inadequate Or No Purge
Root causes
Root CAUSE analysis
Failure to properly venting hydrogen was a component of the ROOT CAUSE. If this happened because of inadequate procedures or human error is not explained. However, venting alone is often not enough to guarantee hydrogen-free atmosphere in complex enclosures, and careful design is required.

Facility

Application
Steel And Metals Industry
Sub-application
Tungsten production
Hydrogen supply chain stage
All components affected
furnace
Location type
Confined
Location description
Unknown
Operational condition
Unknown (No additional details provided)
Description of the facility/unit/process/substances
DESCRIPTION OF THE PROCESS
Tungsten is primarily found in ores like wolframite and scheelite. The refining to metallic tungsten is a hydrometallurgical process which first remove impurities and produce high-purity ammonium paratungstate (APT) or tungsten trioxide (WO3).
This first step is then followed by a reduction step using hydrogen in stationary furnaces at temperatures ranging from 550° to 850° C.

Emergency & Consequences

Number of injured persons
1
Number of fatalities
0
Currency
US$
Property loss (onsite)
7000

Event Nature

Release type
gas
Involved substances (% vol)
H2 100%
Ignition delay
Hot surface

References

Reference & weblink

Table II - Industrial Incidents of Appendix A of Zalosh and Short<br />
COMPARATIVE ANALYSIS OF HYDROGEN FIRE AND EXPLOSION INCIDENTS<br />
Quarterly Report No. 2 for Period December 1, 1977 - February 28, 1978<br />
https://www.osti.gov/biblio/6566131<br />
(accessed September 2020)

JRC assessment