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Clean Hydrogen Partnership

Explosion of a reactor for the hydrogenation of ethylene

Event

Event ID
474
Quality
Description
An excess of hydrogen in the reactor vessel resulted in a runaway reaction, causing the vessel to rupture due to overheating. The unbalanced reaction was caused by a reduction of flow of impure ethylene. When the vessel ruptured, air accessed the vessel and ignited spontaneously the process gas.

[Zalosh and Short, 1978]
Event Initiating system
Classification of the physical effects
Hydrogen Release and Ignition
Nature of the consequences
Macro-region
North America
Country
United States
Date
Main component involved?
Reactor / Oven / Furnace / Test Chamber
How was it involved?
Rupture
Initiating cause
Run-Away Reaction
Root causes
Unknown (No additional details provided)

Facility

Application
Chemical Industry
Sub-application
hydrogenaton of ethylene
Hydrogen supply chain stage
All components affected
reactor vessel
Location type
Confined
Location description
Unknown
Operational condition

Emergency & Consequences

Number of injured persons
0
Number of fatalities
0
Currency
US$
Property loss (onsite)
5000

Event Nature

Release type
gas mixture
Involved substances (% vol)
H2,
C2H4
Ignition delay
Auto-ignition

References

Reference & weblink

Table II - Industrial Incidents of Appendix A of Zalosh and Short<br />
COMPARATIVE ANALYSIS OF HYDROGEN FIRE AND EXPLOSION INCIDENTS<br />
Quarterly Report No. 2 for Period December 1, 1977 - February 28, 1978<br />
https://www.osti.gov/biblio/6566131<br />
(accessed September 2020)

JRC assessment