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Clean Hydrogen Partnership

Explosion at a pipeline of a petrochemical plant

Event

Event ID
1049
Quality
Description
A gas mixture (25% nitrogen, 73% of hydrogen, 2% methane) leaked, due to the ejection of the check valve from its connection with the inlet pipe. A large amount of the gas mixed with air and ignited, probably due to sparks generated by the ejected check hitting a metal pipe. It followed an explosion and a fire. Its pressure wave hit a gas pipeline causing its fracture and a fire. After about 1 hour and 30 minutes the fire was under control. The shockwave from the explosion caused a gas pipe at the back of the workshop to crack and leak, causing a large fire.
Event Initiating system
Classification of the physical effects
Hydrogen Release and Ignition
Nature of the consequences
Macro-region
Asia
Country
China
Date
Main component involved?
Valve (Check)
How was it involved?
Leak & Formation Of A Flammable H2-Ch4-Mixture
Initiating cause
Wrong Component
Root causes
Root CAUSE analysis
The INITIATING cause of the incident was the sudden falling-off of the check valve, due to a large deviation of the dimension of the small diameter of the inner flange thread. Its diameter was too small and eventually lead to the separation of two connections.
The ROOT CAUSE was related to quality control not properly done and failure in inspection.

Facility

Application
Petrochemical Industry
Sub-application
unspecified
Hydrogen supply chain stage
All components affected
check valve, pipe
Location type
Open
Location description
Industrial Area
Operational condition

Emergency & Consequences

Number of injured persons
11
Number of fatalities
2
Currency
Euro
Property loss (onsite)
57000
Post-event summary
2 fatalities, 11 injured persons (out of which 6 were severely injured). Damage estimated around 57K Euro

Lesson Learnt

Lesson Learnt

The plant operator has to establish and implement a qualification system for purchased components.
This will allow the early detection of wrong or not certified materials. Moreover, an inspection system has to be in place, to assess additional risks related to components replacements and repair.

Event Nature

Release type
gas mixture
Involved substances (% vol)
H2 73%,
N2 25%,
CH4 2%
Presumed ignition source
Mechanical sparks

References

Reference & weblink

ICEMSAFE report available at<br />
https://www.ichemsafe.com/info/3275.html <br />
(last retrieved 20.02.2023)

B.Wang et al., Hydrogen related accidents and lesson learned from events reported in the<br />
in east continental Asia,#2023, ICHS-2023

JRC assessment