Skip to main content
Clean Hydrogen Partnership

Explosion in a hydrogenation unit of a refinery

Event

Event ID
679
Quality
Description
The event occurred at a hydrogen processing unit of the refinery. A mixture of hydrocarbon and hydrogen leaked ad the 90-debrees-elbow of a carbon steel pipe. The mixture formed a cloud which exploded.

The investigation concluded that the failure of the line was the result of the thinning of the carbon steel elbow due to long-term erosion/corrosion.
The explosion was followed by fires which caused extensive damage to the hydrocracker, hydro-desulphurisation, and hydrogen processing units.
The explosion is classified by one of the source (Oral et al.) as a Vapour Cloud Explosion (VPE).

Event Initiating system
Classification of the physical effects
Hydrogen Release and Ignition
Nature of the consequences
Macro-region
North America
Country
United States
Date
Main component involved?
Pipe
How was it involved?
Leak & Formation Of A Flammable H2-Hc-Air Mixture
Initiating cause
Material Degradation (Internal Corrosion / Erosion)
Root causes
Root CAUSE analysis
INITIATING cause was the failure of a pipe due corrosion.
Inspection was possibly not able to detect the damage, but it is not known if this was due to limitation of the non-destructive equipment , to the absence of the correct inspection schedule or incorrect assessment of the risk and consequences. ICHEME/MHIDS reproted a wrong dimension of the failed part, which suggest A ROOT CAUSE related to installation errors, wit ha contribution from an inadequate inspection.

Facility

Application
Petrochemical Industry
Sub-application
hydrogenation unit
Hydrogen supply chain stage
All components affected
Pipe and valve
Location type
Confined
Location description
Industrial Area
Operational condition

Emergency & Consequences

Number of injured persons
0
Number of fatalities
16
Currency
US$
Property loss (onsite)
78800000
Property loss (offsite)
550000
Post-event summary
The fire was visible from 32 km away. People in a 5 sq. km area were evacuate. Material damage is significant ($ 78.3 million).
Los Angeles Times reproted 14 light injuries, Rigas&Amyotte 16.
Official legal action
The company had to pay a $550,000 penalty to the South Coast Air Quality Management District in a settlement stemming from the 1992 explosion and other violations.
[https://www.latimes.com/archives/la-xpm-1994-08-10-me-25508-story.html, accessed November 2025]

Event Nature

Release type
gas mixture
Involved substances (% vol)
H2 hydrocarbon
Presumed ignition source
Not reported
Ignition delay
seconds

References

Reference & weblink

MARSH report, 100 largest losses in the hydrocarbon industry, 27th edition 2022<br />
https://www.marsh.com/cz/en/industries/energy-and-power/insights/100-la… />
(accessed January 2024)

ARIA database<br />
event 11282<br />
https://www.aria.developpement-durable.gouv.fr/accident/11282/<br />
(accesed November 2025)<br />

Event 5815 of the UK database ICHEME/MHIDAS <br />
The database is no longer available , but data can be download as PDF .<br />
https://www.icheme.org/knowledge/safety-centre/resources/accident-data/… />
(accessed October 2020)<br />

Los Angeles news <br />
https://www.latimes.com/archives/la-xpm-1992-10-09-mn-724-story.html<br />
(accwssed November 2025)

Rigas F., Amyotte P., Hydrogen safety, Green chemistry and chemical engineering, CRC Press, Taylor & Frances Group; 2012. ISBN-13: 978-1439862315

JRC assessment