Event
- Event ID
- 838
- Quality
- Description
- The explosion occurred during repair work on a boiler. A technician had previously descaled the device using hydrochloric acid, after which he performed the neutralisation step with soda and drained the passivated acid.
The significant scaling on the boiler required a second acid injection, followed by welding work, but this time the rest of the acid had not been drained from the boiler.
Hydrogen emitted by a metal + acid reaction was the cause of this accident. An employee wound up in hospital in a coma.
Labour inspection authorities noted that operating conditions were not respecting environmental protection requirements, i.e. failure to control discharge pH.
They also noted the absence of written procedures. - Event Initiating system
- Classification of the physical effects
- Hydrogen Release and Ignition
- Nature of the consequences
- Macro-region
- Europe
- Country
- France
- Date
- Root causes
- Root CAUSE analysis
- INITIATING cause was failure to perform an operative step
This caused the formation of hydrogen from the reaction of hydrochloric acid with metals, in presence of a hot source (welding).
Root cause (probably) found to be the absence of any written procedure.
Facility
- Application
- Other
- Sub-application
- Boilers industry
- Hydrogen supply chain stage
- All components affected
- Workshop for maintenance of boilers, hydochloric acid
- Location type
- Confined
- Operational condition
- Pre-event occurrences
- The explosion occurred during repair work on a boiler.
Emergency & Consequences
- Number of injured persons
- 1
- Number of fatalities
- 0
- Post-event summary
- An employee wound, in hospital in a coma.
- Official legal action
- Labour inspection authorities noted that operating conditions were not favourable towards environmental protection, i.e. failure to control discharge pH, absence of written procedures.
Event Nature
- Release type
- Gas-liquid-solid mixture
- Involved substances (% vol)
- NaHO,
metals,
H2 - Presumed ignition source
- Welding
References
- Reference & weblink
ARIA data base <br />
event no. 28569
JRC assessment
- Sources categories
- ARIA