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Clean Hydrogen Partnership

Explosion on a cold box

Event

Event ID
663
Quality
Description
An explosion occurred in a nitrogen wash cold box (outside the equipment) after a several day cold shutdown followed by a derime with nitrogen. It is assumed that ice may have split tubes permitting carbon monoxide and hydrogen to leak into the perlite installation. It is likewise assumed that the insulation had channelled and had many voids.
However, the insulation was continuously purged with nitrogen and the mechanism of the explosion is still unknown.
Event Initiating system
Classification of the physical effects
Hydrogen Release and Ignition
Nature of the consequences
Macro-region
North America
Country
United States
Date
Main component involved?
Pipe (Weld)
How was it involved?
Rupture & Formation Of A Flammable H2-Hc-Air Mixture
Initiating cause
Material Degradation (Generic)
Root causes
Root CAUSE analysis
The INITIATING CAUSE were cracks in aluminium welds which leaked hydrogen cumulating in the cold box.

A CONTRIBUTING FACTOR was the cold weather which could have caused the formation of ice. Since the cold box thermal insulation, consisting of perlite, was purged with nitrogen, it is unclear why hydrogen and CO could form an explosive atmosphere.

The ROOT CAUSE is not provided. It could nevertheless plausibly attributed to design and/or manufacturing (welding) error.

Facility

Application
Chemical Industry
Sub-application
cryogenic separation of H2 feed gas
Hydrogen supply chain stage
All components affected
cold box
Location type
Unknown
Operational condition
Description of the facility/unit/process/substances
DECRITION OF THE PROCESS
A "derime" is a maintenance procedure used to remove frozen impurities from a cryogenic system, such as a nitrogen or air separation unit. This is done by warming up the equipment and flowing a warm, dry gas through it to melt and purge any accumulated moisture, carbon dioxide, or other contaminants that would otherwise freeze and block the system. The terms "derime," "defrost," "de-ice," and "thaw" are often used interchangeably for this process.

Emergency & Consequences

Number of injured persons
0
Number of fatalities
0
Environmental damage
0
Currency
US$
Property loss (onsite)
1900000

Event Nature

Release type
gas mixture
Involved substances (% vol)
H2
CO
Release duration
unknown
Presumed ignition source
Static electricity

References

Reference & weblink

Event description extracted from the UK database ICHEME in PDF.<br />
The <br />
https://www.icheme.org/knowledge/safety-centre/resources/accident-data/ <br />
(accessed October 2020)

Table III of Appendix A of Zalosh and Short<br />
COMPARATIVE ANALYSIS OF HYDROGEN FIRE AND EXPLOSION INCIDENTS<br />
Quarterly Report No. 2 for Period December 1, 1977 - February 28, 1978<br />
https://www.osti.gov/biblio/6566131<br />
(accessed September 2020)

LOSS PREVENTION, VOL. 3.

JRC assessment