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Clean Hydrogen Partnership

Explosion at a chlorine production plant

Event

Event ID
603
Quality
Description
An increase of power surge affected the electrolytic chlorine production unit resulting in an excess of H2 in cells, which ignited and exploded.

[Zalosh and Short, 1978]
Event Initiating system
Classification of the physical effects
Hydrogen Release and Ignition
Nature of the consequences
Macro-region
North America
Country
United States
Date
Main component involved?
Electrolytic Cell
How was it involved?
Internal Explosion H2-Cl2 Mixture)
Initiating cause
Malfunctioning (Electrolyser, Cross-Over)
Root causes
Unknown (No additional details provided)

Facility

Application
Chemical Industry
Sub-application
chlorine production
Hydrogen supply chain stage
Location type
Confined
Location description
Unknown
Operational condition
Description of the facility/unit/process/substances
Hydrogen in chlorine has a wide flammability range between approximately 5% and 95%. The reaction is highly exothermic and characterise by a low ignition energy.

Emergency & Consequences

Number of injured persons
0
Number of fatalities
0
Currency
US$
Property loss (onsite)
69000

Event Nature

Release type
gas mixture
Involved substances (% vol)
H2,
Cl2
Ignition delay
Short circuit

References

Reference & weblink

Table II - Industrial Incidetns of Appendix A of Zalosh and Short<br />
COMPARATIVE ANALYSIS OF HYDROGEN FIRE AND EXPLOSION INCIDENTS<br />
Quarterly Report No. 2 for Period December 1, 1977 - February 28, 1978<br />
https://www.osti.gov/biblio/6566131<br />
(accessed September 2020)

JRC assessment