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Clean Hydrogen Partnership

Explosion in a chlorine production plant

Event

Event ID
506
Quality
Description
Vented hydrogen flew back into the system and exploded. Hydrogen was not vented fast enough and exceed the lower flammability limit (4% in volume).

[Zalosh and Short, 1978]
Event Initiating system
Classification of the physical effects
Hydrogen Release and Ignition
Nature of the consequences
Macro-region
North America
Country
United States
Date
Main component involved?
Electrolytic Cell
How was it involved?
Internal Explosion (H2-Air Mixture)
Initiating cause
Inadequate Venting
Root causes
Root CAUSE analysis
The hydrogen backflow was due to a too high hydrogen production rate, which the venting system could not deal with. This suggests a ROOT CAUSE related to wrong operations. Another causal factor could be speculatively assigned to a vent design not fit for the purpose.

Facility

Application
Chemical Industry
Sub-application
Ammonia production
Hydrogen supply chain stage
Location type
Confined
Location description
Unknown
Operational condition
Unknown (No additional details provided)

Emergency & Consequences

Number of injured persons
0
Number of fatalities
0
Currency
US$
Property loss (onsite)
90000

Event Nature

Release type
gas mixture
Involved substances (% vol)
H2,
Cl2
Ignition delay
Not reported

References

Reference & weblink

Table II - Industrial Incidents of Appendix A of Zalosh and Short<br />
COMPARATIVE ANALYSIS OF HYDROGEN FIRE AND EXPLOSION INCIDENTS<br />
Quarterly Report No. 2 for Period December 1, 1977 - February 28, 1978<br />
https://www.osti.gov/biblio/6566131<br />
(accessed September 2020)

JRC assessment