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Clean Hydrogen Partnership

Deflagration in a ammonia synthesis unit

Event

Event ID
90
Quality
Description
A deflagration occurred during shutdown of a reactor used for ammonia synthesis. It was followed by a jet fire.
The hydrogen leak was probably due first to the lower seals, followed by another leak on the upper seal of the autoclave, under 15 to 20 bars.

The Internal Operation Plan is launched and cancelled 1h50 later. No one is injured.
Event Initiating system
Classification of the physical effects
Hydrogen Release and Ignition
Nature of the consequences
Macro-region
Europe
Country
France
Date
Main component involved?
Reactor / Oven / Furnace / Test Chamber
How was it involved?
Leak & Formation Of A Flammable H2-Air Mixture
Initiating cause
Unknown
Root causes
Unknown (No additional details provided)
Root CAUSE analysis
INITIATING cause was the leak of a joint of an autoclave. Nothing known on the root cause(s).

Facility

Application
Chemical Industry
Sub-application
Production of fertilisers
Hydrogen supply chain stage
All components affected
autoclave, seals of joints
Location type
Unknown
Location description
Industrial Area
Operational condition
Pre-event occurrences
The leak occurred during maintenance operation

Emergency & Consequences

Number of injured persons
0
Number of fatalities
0
Emergency action
Emergency responders were dispatched to the scene. The facility deluge system was turned on. This system covers the trailer fill aisle with water and includes nozzles at the rear of the trailer and a fire cannon directed to the front. When the emergency responders arrived, they immediately began spraying the adjacent trailers to ensure that they stayed cool. The HazMat crews closed the 10 individual tube fill isolation valves located at the rear of the tube trailer and extinguished the fire. Total time to control the incident was less than 10 minutes and there was no property damage from this event.

Event Nature

Release type
Liquid
Involved substances (% vol)
H2 100%
Actual pressure (MPa)
20
Presumed ignition source
Not reported
Deflagration
Y
High pressure explosion
N
High voltage explosion
N
Flame type
Jet flame

References

Reference & weblink

Event no. 31715 of the French database ARIA (accessed December 2020)

JRC assessment